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CHAPTER 2
Atoms, Molecules, and Ions
■
SOLUTIONS TO EXERCISES
Note on significant significant figures: If the final answer to a solution needs to be rounded off, it is given first with
one nonsignificant figure, and the last significant figure is underlined. The final answer is then rounded to the correct number of significant figures. In multistep problems, problems, intermediate answers are given with at least one nonsignificant figure; however, only the final answer a nswer has been rounded off. 2.1.
The element element with atomic number 17 (the (the number number of of protons protons in the nucleus) nucleus) is chlorine, chlorine, symbol symbol 35 Cl. The mass number is 17 + 18 = 35. The symbol is Cl.
2.2.
Multiply each isotopic mass by its fractional abundance; then sum: 34.96885 amu 0.75771 36.96590 amu 0.24229
=
26.496247
=
8.956467
35.452714 = 35.453 amu The atomic weight of chlorine c hlorine is 35.453 amu. 2.3.
a.
Se: Group 6A, Period 4; nonmetal nonmetal
b.
Cs: Group 1A, Period 6; metal
c.
Fe: Group 8B, Period 4; metal
d.
Cu: Group 1B, Period 4; metal
e.
Br: Group 7A, Period 4; nonmetal
2.4.
Take as as many many cations as there are are units units of of charge charge on the anion anion and as many many anions as there are + units of charge on the cation. Two K ions have a total charge of 2+, and one CrO42 ion has a charge of 2, giving a net charge of zero. The simplest ratio of K + to CrO42 is 2:1, and the formula is K 2CrO4.
2.5.
a.
CaO: Calcium, Calcium, a Group 2A metal, is expected to form only a 2+ ion (Ca2+, the calcium ion). Oxygen (Group 6A) is expected to form an anion of charge equal to the group number minus 8 (O2−, the oxide ion). The name of the compound is calcium oxide.
b. PbCrO4: Lead has more than one monatomic ion. You can find the charge on the Pb ion if you know the formula of the anion. From Table 2.5, the CrO4 refers to the anion CrO42 (the chromate ion). Therefore, the Pb cation must be Pb2+ to give electrical neutrality. The name of Pb2+ is lead(II) ion, so the name of the compound is lead(II) lead(II) chromate. 2.6.
Thallium(III) Thallium(III) nitrate contains the thallium(III) thallium(III) ion, Tl3+, and the nitrate ion, NO3. The formula is Tl(NO3)3. 34
Chapter 2: Atoms, Molecules, and Ions
2.7.
a.
Dichlorine hexoxide
b.
Phosphorus trichloride trichloride
c.
Phosphorus pentachloride pentachloride
35
2.8.
a. CS2
2.9.
a. Boron trifluoride
2.10.
When you remove remove one H+ ion from HBrO4, you obtain the BrO4 ion. You name the ion from the acid by replacing -ic with -ate. The anion is called the perbromate ion.
2.11.
Sodium carbonate decahydrate
2.12.
Sodium thiosulfate is composed of sodium ions (Na+) and thiosulfate ions (S2O32), so the formula of the anhydrous compound is Na2S2O3. Since the material is a pentahydrate, the formula f ormula of the compound is Na2S2O35H2O.
2.13.
Balance O first in parts (a) and (b) because because it occurs occurs in only one product. Balance S first in part (c) because it appears in only one product. Balance H first in part (d) because it appears in just one reactant as well as in the product. a.
b. SO3 b. Hydrogen selenide
Write a 2 in front of POCl3 for O; this requires a 2 in front of PCl3 for final balance: O2 + 2PCl3 2POCl3
b.
Write a 6 in front of N2O to balance O; this requires a 6 in front of N2 for final balance: P4 + 6N2O P4O6 + 6N2
c.
Write 2As2S3 and 6SO2 to achieve an even number of oxygens on the right to balance what will always be an even number of oxygens on the left. The 2As2S3 then requires 2As2O3. Finally, to balance (6 + 12) O's on the right, write 9O2. 2As2S3 + 9O2 2As2O3 + 6SO2
d.
Write a 4 in front of H3PO4; this requires a 3 in front of Ca(H2PO4)2 for twelve H's. Ca3(PO4)2 + 4H3PO4 3Ca(H2PO4)2
■
ANSWERS TO CONCEPT CHECKS
2.1.
CO2 is a compound that is a combination of 1 carbon atom and 2 oxygen atoms. atoms. Therefore, the chemical model must contain a chemical combination of 3 atoms stuck together with 2 of o f the atoms being the same (oxygen). Since each 'ball' represents an individual atom, the three models on the left can be eliminated since they don't don't contain the correct number of atoms. Keeping in mind that balls of the same color represent the same element, only the model on the far right contains two elements with the correct ratio of atoms, 1:2; therefore, it must be CO2.
2.2.
If 7999 out of 8000 alpha particles deflected back at the alpha-particle source, this would imply that the atom was a solid, impenetrable mass. Keep in mind that this is in direct contrast to what was observed in the actual experiments, experiments, where the majority of the alpha particles passed through without being deflected.
36
Chapter 2: Atoms, Molecules, and Ions
2.3.
Elements are listed together in groups because they have similar chemical and/or physical properties.
2.4.
Statement (a) is the best statement regarding regardi ng molecular compounds. Although you may have wanted to classify Br 2 as a molecular compound, it is an element and not a compound. Regarding statement (b), quite a few molecular compounds exit that don’t contain carbon. Water and the nitrogen oxides associated with smog are prime examples. Statement (c) is false; ionic compounds consist of anions and cations. Statement (d) is very close to the right selection but it is too restrictive. Some molecular compounds containing both metal and nonmetal atoms are known to exist, e.g., cisplatin, Ni(CO)4, etc. Because numerous molecular compounds are either solids or liquids at room temperature, statement (e) is false. f alse.
2.5.
a.
This compound compound is an ether because it has a functional group of an oxygen oxygen atom between two carbon atoms ( – ). – O – ).
b.
This compound compound is an alcohol because because it has an – OH OH functional group.
c.
This compound compound is a carboxylic acid because it has the – COOH COOH functional group.
d.
This compound compound is a hydrocarbon because it contains only carbon and hydrogen atoms. atoms.
2.6.
The SO42-, NO2-, and I3- are considered to be polyatomic ions. Statement (a) is true based on the prefix poly. By definition, any ion must have a negative or positive charge; thus, statement (b) is true. Bring that the triiodide ion has only iodine atoms bonded together, and no other elements present, statement statement (c) is false. There are numerous numerous examples to show show that statement statement (d) is true, e.g., chromate, dichromate, permanganate to name a few. Oxoanions are polyatomic ions containing a central characteristic element surrounded by a number of oxygen atoms, e.g., sulfate and nitrite given in this concept check ’s. Statement (e) is true.
2.7.
A bottle containing a compound with the formula Al2Q3 would have an anion, Q, with a charge of 2. The total positive charge in the compound due to the Al3+ is 6+ (2 x 3+), so the total negative charge must be 6; therefore, each Q ion must have a charge of 2. Thus, Q would probably be an element from Group 6A on the periodic table.
■
ANSWERS TO SELF-ASSESSMENT AND AND REVIEW REVIE W QUESTIONS
2.1.
Atomic theory is an explanation of the structure of matter matter in terms of different different combinations combinations of of very small particles called atoms. Since compounds are composed of atoms of two or more elements, there is no limit to the number of ways in which the elements can be combined. Each compound has its own unique properties. A chemical reaction consists of the rearrangement of the atoms present in the reacting substances to give new chemical combinations present in the substances formed by the reaction.
2.2.
Divide each amount of chlorine, chlorine, 1.270 g and 1.904 g, by the lower lower amount, amount, 1.270 g. This gives gives 1.000 and 1.499, respectively r espectively.. Convert these to whole numbers by multiplying by 2, giving 2.000 and 2.998. The ratio of these amounts of chlorine is essentially 2:3. This is consistent with the law of multiple proportions because, for a fixed mass of iron (1 gram), the masses of chlorine in the other two compounds are in a ratio of small whole numbers.
Chapter 2: Atoms, Molecules, and Ions
37
2.3.
A cathode-ray tube consists of a negative negative electrode, or cathode, and a positive positive electrode, or anode, in an evacuated tube. Cathode rays travel from the cathode to the anode when a high voltage is turned on. Some of the rays pass through the hole in the anode to form a beam, which is then bent toward positively charged charged electric plates in the tube. This implies that a cathode ray consists of a beam of negatively negatively charged particles (or (or electrons) and that that electrons are constituents of all matter.
2.4.
Millikan performed a series series of of experiments experiments in which he obtained the charge on the the electron electron by observing how a charged drop of oil falls in the presence and in the absence of an electric field. An atomizer introduces a fine mist of oil drops into the top chamber (Figure 2.6). Several drops happen to fall through a small hole into the lower chamber, where the experimenter follows the motion of one drop with a microscope. Some of these drops have picked up one or more electrons as a result of friction in the atomizer and have become negatively charged. A negatively charged drop will be attracted upward when the experimenter turns on a current to the electric plates. The drop’s upward speed (obtained by timing its rise) is related to its mass-to-charge ratio, from which you can calculate the charge on the electron.
2.5.
The nuclear model of the the atom is based on experiments of Geiger, Marsden, and Rutherford. Rutherford stated that most of the mass of an atom is concentrated in a positively charged center called the nucleus around which negatively charged electrons move. The nucleus, although it contains most of the mass, occupies only a very small portion of the space of the atom. Most of the alpha particles passed through the metal atoms of the foil undeflected by the lightweight electrons. When an alpha particle does happen to hit a metal-atom nucleus, it is scattered at a wide angle because it is deflected by the massive, positively positively charged nucleus (Figure 2.8).
2.6.
The atomic atomic nucleus consists of two kinds of particles, particles, protons and neutrons. neutrons. The mass of each is 27 about the same, on the order of 1.67 x 10 kg, and about 1800 times that of the electron. An electron has a much smaller mass, on the order of 9.11 x 1031 kg. The neutron is electrically neutral, but the proton is positively charged. An electron is negatively charged. The charges on the proton and the electron are equal in magnitude.
2.7.
Protons (hydrogen nuclei) were discovered as products of experiments involving the collision of alpha particles with nitrogen atoms that resulted in a proton being knocked out of the nitrogen nucleus. Neutrons were discovered as the radiation product of collisions of alpha particles with beryllium atoms. atoms. The resulting radiation radiation was discovered discovered to consist of particles particles having a mass mass approximately equal equal to that of a proton and having no charge (neutral).
2.8.
Oxygen consists of three different isotopes, each having 8 protons but a different different number number of neutrons.
2.9.
The percentages of the different isotopes in most naturally occurring elements have remained essentially constant over time time and in most cases are independent of the origin of the element. Thus, what Dalton actually calculated were average atomic a tomic weights (relative weights). He could not weigh individual atoms, atoms, but he could find the average mass of one atom relative to the average mass of another.
2.10.
A mass mass spectrometer spectrometer measures measures the mass-to-charge mass-to-charge ratio of positively positively charged atoms (and molecules). It produces a mass spectrum, spectrum, which shows the relative numbers of atoms (fractional abundances) of various masses (isotopic masses). The mass spectrum gives us all the information needed to calculate the atomic atomic weight.
38
Chapter 2: Atoms, Molecules, and Ions
2.11.
The atomic atomic weight of an element is the average atomic weight for the naturally naturally occurring occurring element expressed in atomic mass units. The atomic weight would be different elsewhere in the universe if the percentages of isotopes in the element were different from those on earth. Recent research has shown that isotopic abundances actually do differ slightly depending on the location found on earth.
2.12.
The element element in Group 4A and Period 5 is tin (atomic number 50).
2.13.
Am metal etal is a substance or mixture mixture that has has characteristic characteristic luster, luster, or shine, and is generally a good conductor of heat and electricity.
2.14.
The formula for ethane is C2H6.
2.15.
A molecular molecular formula formula gives gives the exact number number of different different atoms atoms of an element in a molecule. A structural formula is a chemical formula that shows how the atoms are bonded to one another in a molecule.
2.16.
Organic molecules molecules contain carbon carbon combined combined with with other other elements such as hydrogen, oxygen, and nitrogen. An inorganic molecule is composed of elements other than carbon. Some inorganic molecules that contain carbon are carbon monoxide (CO), carbon dioxide (CO2), carbonates, and cyanides.
2.17.
An ionic binary compound: NaCl; a molecular molecular binary compound: H2O.
2.18.
a.
The elements are represented by B, F, and I.
b.
The compounds are represented represented by A, E, and G.
c.
The mixtures are represented by C, D, and H.
d.
The ionic solid is represented by A.
e.
The gas made up of an element and a compound is represented by C.
f.
The mixtures of elements are represented by D and H.
g.
The solid element is represented by F.
h.
The solids are represented by A and F.
i.
The liquids are represented by E, H, and I.
2.19.
In the Stock Stock system, CuCl is called called copper(I) chloride, and CuCl2 is called copper(II) chloride. One of the advantages of the Stock system is that more than two different ions of the same metal ic and -ous can be named with this system. In the former (older) system, a new suffix other than -ic must be established and/or memorized.
2.20.
A balanced balanced chemical chemical equation equation has the numbers numbers of atoms of each element equal on both sides sides of the arrow. The coefficients are the smallest possible whole numbers.
2.21.
The answer is a: 50 p, 69 n, and 48 e – .
2.22.
The answer is d: 65%.
2.23.
The answer is c: magnesium hydroxide, Mg(OH)2.
Chapter 2: Atoms, Molecules, and Ions
2.24. ■
2.25.
39
The answer is b: Li.
ANSWERS TO CONCEPT EXPLORATIONS EXPLORATIONS Part I
a.
Average mass =
2.00g 2.00g + 2.00g 2.00g + 2.00g 2.00g + 2.00g 2.00g 4
= 2.00 g
2.00g 2.00g + 1.75g 1.75g + 3.00g 3.00g + 1.25g 1.25g 4
= 2.00 g
Part II
a.
Average mass =
b.
The average mass of a sphere in in the two samples samples is the same. same. The average does not represent the individual masses. Also, it does not indicate the variability in the individual masses.
Part III
a.
b.
50 bluespheres bluespheres 1
2.00g = 100.00 g 1 blue sphere
If 50 spheres were removed removed at random, then 50 50 spheres would remain in the jar. You You can use the average mass to calculate the total mass. 50spheres 50spheres 2.00g 2.00g = 100.00 g 1 sphere 1
c.
No, the average mass does not represent the mass of an individual sphere.
d.
80.0g 80.0g 1
1 bluesphere bluesphere 2.00 g
e.
60.0g 60.0g 1
1sphere = 30.0 spheres 2.00 g
= 40.0 blue spheres
The assumption is that the average mass of a sphere (2.00 ( 2.00 g) can be used in the calculation. Also, assume the sample is well mixed. Part IV
a.
For green spheres: X =
For blue spheres: X =
b.
3green = 0.750 3 green + 1 blue 1 blue = 0.250 3 green + 1 blue
Average mass = (0.750)
3.00g
+ (0.250) 1 green sphere
1.00g 1 blue sphere
= 2.50 g
c.
The atomic atomic weight of an element is the the weighted weighted average calculated as in part part (b) (b) of Part IV above, using fractional abundances and individual masses.
40
Chapter 2: Atoms, Molecules, and Ions
2.26.
a.
Atom A has three protons.
b.
The number of protons is the same as the atomic number number for that element.
c.
Lithium, Li, has atomic number 3.
d.
The charge on element A is zero. There T here are three protons, each +1, and three electrons, each 1. This yields a net charge of zero.
e.
The nuclide symbol for A is 73 Li .
f.
Atom B has three protons and thus atomic number 3. ItIt is lithium, with symbol symbol Li. Li.
g.
Atom B has three protons and three neutrons. Its mass number is 6. This is different from the mass number of atom A, which is 7.
h.
Atom B has three protons and three electrons and thus is neutral.
i.
The nuclide symbol for B is 63 Li . The atomic atomic number is 3 and the mass number is 6 for both nuclides.
e p e
n
n p
n p 6
j.
3
Li
e
e
p n
e
n p
n
e
p
6 3
Li
In both cases the mass number is 6 and a nd the atomic number is 3
■
k.
Two different lithium isotopes are depicted, lithium-6 and lithium-7. lithium-7.
l.
The mass mass number of an an isotope is the total number of protons and neutrons in its nucleus. Its value is an integer. It is related to the mass of the isotope but not related to the atomic weight, which is a weighted average over the fractional abundances and isotopic masses.
ANSWERS TO CONCEPTUAL PROBLEMS
2.27.
If atoms atoms were balls balls of positive charge with the electrons electrons evenly distributed throughout, there would be no massive, positive positive nucleus to deflect the beam of alpha particles when it is shot at the gold foil.
2.28.
Once the subscripts of the compounds compounds in the original original chemical chemical equation are changed changed (the molecule N2 was changed to the atom N), the substances reacting are no longer the same. Your friend may be able to balance the second equation, but it is no longer the same chemical reaction.
2.29.
You could group group elements elements by similar physical properties such as density, mass, color, conductivity, conductivity, etc., or by chemical properties, such as reaction with air, reaction with water, etc.
2.30.
You would name the ions with the formulas XO42, XO32, and XO2 using the name for XO22 (excite) as the example to determine the root name of the element X (exc). Thus XO42, with the greatest number of oxygen atoms in the group, would be perexcate; XO32 would be excate; and XO2, with the fewest oxygen atoms in the group, would be hypoexcite.
Chapter 2: Atoms, Molecules, and Ions
2.31.
2.32.
41
a.
In each case, the total positive positive charge and the total negative charge in the compounds must must cancel. Therefore, the compounds compounds with the cations c ations X+, X2+, and X5+, combined with the SO42 anion, are X2SO4, XSO4, and X2(SO4)5, respectively. respectively.
b.
You recognize the fact fact that whenever a cation can have multiple multiple oxidation states states (1+, 2+, and 5+ in this case), the name of the compound must indicate the charge. Therefore, the names of the compounds in part (a) would be exy(I) sulfate, exy(II) sulfate, and exy(V) sulfate, respectively. respectively.
a.
This model contains three atoms atoms of two different elements (H and O). Therefore, the model is of H2O.
b.
This model represents represents a crystal that contains contains two different different elements in a 1:1 ratio + (K and Cl). Therefore, the model represents the ionic compound, KCl.
c.
This model contains six atoms, atoms, four of which which are the the same (H), and two others (C and O). Therefore, the model is of CH3OH.
d.
This model contains four atoms atoms of two two different elements (N and H). Therefore, the model is of NH3.
2.33.
A potassium-39 potassium-39 atom in this case would would contain contain 19 protons and 20 neutrons. neutrons. If If the charge of the proton were twice that that of an electron, it would take twice as many many electrons as protons, protons, or 38 electrons, to maintain a charge of zero.
2.34.
a.
Since the mass of an atom is not due only to the sum of the masses of the protons, neutrons, and electrons, when you change the element in which you are basing the amu, the mass of the amu must change as well.
b.
Since the amount of material that makes up a hydrogen atom doesn’t change, when the amu gets larger, as in this problem, the hydrogen atom must have a smaller mass in amu.
a.
2Li + Cl2 2LiCl
b.
16Na + S8 8Na2S
c.
2Al + 3I2 2AlI3
d.
3Ba + N2 Ba3 N N2
e.
12V + 5P4 4V3P5
2.35.
2.36.
a. b.
2A + B2 2AB
c.
Some possible real elements with formula B2 are F2, Cl2, Br 2, and I2.
42
■
Chapter 2: Atoms, Molecules, and Ions
SOLUTIONS TO PRACTICE PROBLEMS
Note on significant significant figures: If the final answer to a solution needs to be rounded off, it is given first with
one nonsignificant figure, and the last significant figure is underlined. The final answer is then rounded to the correct number of significant significant figures. In multistep multistep problems, intermediate answers are given with at least one nonsignificant figure; however, only the final answer a nswer has been rounded off. 2.37.
a. Helium
b. Hydrogen
2.38.
a. Beryllium
2.39.
a. K
2.40.
a. Cu
2.41.
The mass mass of the electron electron is found found by multiplying multiplying the the two values:
b. S b. Ca
1.602 x 1019 C
2.42.
c. Palladium
b. Silver c. Fe
c. Silicon
d. Strontium d. Carbon
d. Mn
c. Hg
d. Sn
5.64 1012 kg = 9.035 1031 kg = 9.04 1031 kg 1C
The mass mass of the fluorine fluorine atom atom is found by multiplying multiplying the two two values: 1.602 1019 C
1.97 107 kg 1C
= 3.155 1026 kg = 3.16 1026 kg
2.43.
The isotope of atom A is the atom with with 18 protons, protons, atom atom C; the atom that has the the same same mass number as atom A (37) is atom D.
2.44.
The isotope of atom A is the atom with with 32 protons, protons, atom atom D; the atom that has the same same mass number as atom A (71) is atom B.
2.45.
Each isotope isotope of chlorine chlorine (atomic (atomic number 17) has 17 protons. protons. Each neutral atom will also have have 17 electrons. The number of neutrons for Cl-35 is 35 – 17 17 = 18 neutrons. The number of neutrons for Cl-37 is 37 – 17 17 = 20 neutrons.
2.46.
Each isotope isotope of nitrogen (atomic number 7) has seven protons. Each Each neutral neutral atom will also have seven electrons. The number of neutrons for N-14 is 14 – 7 7 = 7 neutrons. The number of neutrons for N-15 is 15 – 7 7 = 8 neutrons.
2.47.
The element element with 11 11 protons in its nucleus is sodium (Na). The mass mass number = 11 + 12 = 23. The 23 notation for the nucleus is 11 Na .
2.48.
The element element with 34 protons in its nucleus is selenium selenium (Se). The mass number = 34 + 45 = 79. The notation for the nucleus is 7934Se .
2.49.
Since the atomic atomic ratio of nitrogen nitrogen to hydrogen is 1:3, divide divide the atomic weight weight of N by one-third of the atomic weight of hydrogen to find the relative atomic weight of N. AtomicweightofN 7.933g 13.901g 13.901g N 13.90 = = = 1 1gH Atomic weight of H 1/3 x 1.712 g
Chapter 2: Atoms, Molecules, and Ions
2.50.
43
Since the atomic ratio of hydrogen hydrogen to sulfur is 2:1, divide divide the atomic atomic weight of of S by by one-half one-half of the atomic weight of hydrogen to find the relative atomic weight of S. 31.8 Atomicweightof weightofS 9.330g 31.78g 31.78gS = = = Atomic weight of H 1/2 x 0.587 g 1 1gH
2.51.
Multiply each isotopic isotopic mass mass by its fractional fractional abundance, abundance, and then then sum: sum: X-63:
62.930 0.6909
=
43.4783
X-65:
64.928 0.3091
=
20.0692
63.5475 The element is copper, atomic atomic weight 63.546 amu. 2.52.
= 63.55 amu
Multiply each isotopic isotopic mass by its fractional fractional abundance, abundance, and then then sum: sum: 49.9472 0.002500
=
50.9440 0.9975
=
0.124868 50.81664
= 50.94150 = 50.94 amu The atomic weight of this element is 50.94 amu. The element is vanadium (V). 2.53.
Multiply each isotopic isotopic mass by its fractional fractional abundance, abundance, and then then sum: sum: 38.964 0.9326
=
39.964 1.00 104 = 40.962 0.0673
36.3378 0.0039964
=
2.75674
= 39.09853 = 39.10 amu The atomic weight of this element is 39.10 amu. The element is potassium (K). 2.54.
Multiply each isotopic isotopic mass by its fractional abundance, and then then sum: 27.977 0.9221
=
25.798
28.976 0.0470
=
1.362
29.974 0.0309
=
0.9262
= 28.086 = 28.09 amu The atomic weight of this element is 28.09 amu. The element is silicon (Si). 2.55.
According to the picture, there are 20 atoms, atoms, 5 of which are brown and 15 of which are green. Using the isotopic masses in the problem, the atomic weight of element X is 5 15 (23.02 amu) + (25.147 amu) = 5.755 + 18.8602 = 24.6152 = 24.615 amu 20 20
2.56.
According to the picture, there are 24 atoms, atoms, 8 of which are blue and 16 of which are orange. Using the isotopic masses in the problem, the atomic weight of element X is 8 16 (47.621 amu) + (51.217 amu) = 15.8737 + 34.1447 = 50.0184 = 50.018 amu 24 24
44
Chapter 2: Atoms, Molecules, and Ions
2.57.
a.
C: Group 4A, Period 2; nonmetal
b.
Po: Group 6A, Period 6; metal
c.
Cr: Group 6B, Period 4; metal
d.
Mg: Group 2A, Period 3; metal
e.
B: Group 3A, Period 2; metalloid
a.
V: Group 5B, Period 4; metal
b.
Rb: Group 1A, Period 5; metal
c.
B: Group 3A, Period 2; metalloid
d.
I: Group 7A, Period 5; nonmetal
e.
He: Group 8A, Period 1; nonmetal
2.58.
2.59.
a.Tellurium
b. Aluminum
2.60.
a. Bismuth
b. Beryllium
2.61.
Examples are:
2.62.
a.
O (oxygen)
b.
F (fluorine)
c.
Fe (iron)
d.
Ce (cerium)
Examples are: a.
Ti (titanium) (titanium)
b.
Li (lithium) (lithium)
c.
S (sulfur)
d.
U (uranium) (uranium)
2.63.
They are different different in that the solid sulfur consists of S8 molecules, whereas the hot vapor consists of S2 molecules. The S8 molecules are four times as heavy as the S2 molecules. Hot sulfur is a mixture of S8 and S2 molecules, but at high enough temperatures only S2 molecules are formed. Both hot sulfur and solid sulfur consist of molecules with only sulfur atoms.
2.64.
They are different different in that the the solid phosphorus consists of P4 molecules, whereas the hot vapor consists of P2 molecules. The P4 molecules are twice as heavy as the P2 molecules. Hot phosphorus is a mixture mixture of P4 and P2 molecules above the boiling point, but at high temperatures only P2 molecules are formed. Both solid phosphorus and phosphorus vapor consist of molecules molecules with only phosphorus atoms.
Chapter 2: Atoms, Molecules, and Ions
2.65.
45
The number number of nitrogen nitrogen atoms in the 4.19-g sample of N2O is 5.73 1022 N2O molecules
2 N atoms = 1.146 1023 N atoms = 1.15 1023 N atoms 1 N2 O molecule
The number of nitrogen atoms in 2.67 g of N2O is 2.67 g N2O
2.66.
Since each HNO3 molecule contains contains one N atom, in 4.30 1022 HNO3 molecules there are 4.30 x 1022 N atoms. The number number of oxygen atoms atoms in 61.0 g of HNO3 is obtained as follows. 61.0 g HNO3
2.67.
2.68.
1.146 1023 N atoms atoms = 7.303 1022 N atoms = 7.30 1022 N atoms atoms 4.19 g N 2 O
4.30 1022 HNO3 molecules 4.50 g HNO3
= 1.749 1024 O atoms = 1.75 1024 O atoms 1 NH3 molecule = 4.0 1022 NH3 molecules 1.2 1023 H atoms 3 H atoms 4.2 1023 H atoms
1C2 H5OHmolecule 6 H atoms
2.69.
2.70.
2.71.
2.72.
2.73.
3 O atoms 1 HNO3 molecule
a.
N2H4
b.
H2O2
c.
C3H8O
d.
PCl3
a.
C3H8O3
b.
Si2H6
c.
NH3O
d.
SF4
a.
PCl5
b.
NO2
c.
C3H6O2
a.
H2SO4
b.
C6H6
c.
C3H6O
1Featom Featom 1 Fe(NO3 ) 2 unit
1Fe(NO3) 2 unit 2 NO ions
= 7.0 1022 C H OH molecules 2
5
1Featom Featom 1 1 NO3 ion = = 3 O atoms 6 O atoms 6
Thus, the ratio of iron atoms to oxygen atoms is one Fe atom to six O atoms.
46
Chapter 2: Atoms, Molecules, and Ions
1 PO3 ion 2.74.
4 O atoms
4
1 (NH ) PO unit 4 3
1 NH unit
4
4
3
1 (NH4 )3PO4 unit
1 PO4 ion
3 NH4 units
4 O atoms =
1 N atom
4 =
3 N atoms
3
Thus, the ratio of oxygen atoms to nitrogen atoms is four O atoms to three N atoms. 2.75.
2.76.
2.77.
2.78.
2.79.
2.80.
2.81.
a.
Fe(CN)3
b.
K 2CO3
c.
Li3 N
d.
Ca3P2
a.
Co3 N2
b.
(NH4)3PO4
c.
Na2SO3
d.
Fe(OH)3
a.
Na2SO4: sodium sulfate (Group 1A forms only 1+ cations.)
b.
Na3 N: sodium nitride (Group 2A forms forms only 1+ cations.)
c.
CuCl: copper(I) copper(I) chloride (Group 1B forms 1+ and 2+ cations.)
d.
Cr 2O3: chromium(III) chromium(III) oxide (Group 6B forms numerous oxidation states.)
a.
CaO: calcium oxide (Group 2A forms only 2+ cations.)
b.
Mn2O3: manganese(III) manganese(III) oxide (Group 7B forms numerous oxidation states.)
c.
NH4HCO3: ammonium bicarbonate or ammonium hydrogen carbonate.
d.
Cu(NO3)2: copper(II) nitrate (Group 1B forms 1+ and 2+ cations.)
a.
Iron(III) phosphate: FePO4 (Phosphate is in Table 2.6.)
b.
Potassium sulfide: K 2S (Group 1A ions form 1+ cations and sulfide is in Table 2.4)
c.
Magnesium carbonate: MgCO3 (Group 2A ions form 2+ cations; carbonate is in Table 2.6.)
d.
Manganese(II) Manganese(II) sulfite: MnSO3 (Sulfite is in Table 2.6.)
a.
Sodium thiosulfate: Na2S2O3 (The S2O32 is in Table 2.6.)
b.
Copper(II) Copper(II) hydroxide: Cu(OH)2 (Two OH- ions must be used to balance Cu2+.)
c.
Calcium hydrogen carbonate: Ca(HCO3)2 (The HCO3 ion is in Table 2.6.)
d.
Chromium(III) Chromium(III) phosphide: CrP (Both ions have charges of 3-.)
a.
Molecular
b.
Ionic
c.
Molecular
d.
Ionic
Chapter 2: Atoms, Molecules, and Ions
2.82.
2.83.
2.84.
2.85.
2.86.
2.87.
2.88.
2.89.
a.
Molecular
b.
Molecular
c.
Molecular
d.
Ionic
a.
Hydrogen iodide
b.
Diphosphorus pent(a)oxide
c.
Arsenic trihydride
d.
Chlorine dioxide
a.
Dinitrogen difluoride
b.
Carbon tetrafluoride
c.
Dinitrogen pent(a)oxide
d.
Tetr(a)arsenic hex(a)oxide
a.
NBr 3
b.
XeF6
c.
CO
d.
Cl2O5
a.
P2O5
b.
NO2
c.
N2F4
d.
BF3
a.
Selenium trioxide
b.
Disulfur dichloride
c.
Carbon monoxide
a.
Nitrogen trifluoride trifluoride
b.
Diphosphorus tetrahydride
c.
Oxygen difluoride
a.
Sulfurous acid: H2SO3
b.
Hyponitrous acid: H2 N N2O2
c.
Disulfurous acid: H2S2O5
d.
Arsenic acid: H3AsO4
47
48
Chapter 2: Atoms, Molecules, and Ions
2.90.
a.
Selenous acid: H2SeO3
b.
Chlorous acid: acid: HClO2
c.
Hypoiodous acid: HIO
d.
Nitric acid: HNO3
2.91.
Na2SO410H2O is sodium sulfate decahydrate.
2.92.
NiSO46H2O is nickel(II) sulfate hexahydrate.
2.93.
Iron(II) sulfate heptahydrate heptahydrate is FeSO47H2O.
2.94.
Cobalt(II) Cobalt(II) chloride hexahydrate is CoCl26H2O. 6 O atoms 3 O atoms 1 Ca(NO3)2 + 1 Na2CO3 = 9 O atoms 1 Ca(NO3 ) 2 unit 1 Na 2CO3 unit
2.95.
2.96.
1Oatom + 2 SO2 2 PbO 1 PbO unit
2Oatoms = 6 O atoms 1 SO2 unit
The equation is not balanced as written. There are currently only 2 oxygen atoms on the left side. 2.97.
a.
Balance: Sn + NaOH Na2SnO2 + H2 If Na is balanced first by writing a 2 in front of NaOH, the entire equation is balanced. Sn + 2NaOH 2NaOH Na2SnO2 + H2
b.
Balance: Al + Fe3O4 Al2O3 + Fe First balance O (it appears once on each side) by writing a 3 in front of Fe3O4 and a 4 in front of Al2O3: Al + 3Fe3O4 4Al2O3 + Fe Now balance Al against against the 8 Al's Al's on the right and Fe against against the 9 Fe's on the left: left: 8Al + 3Fe3O4 4Al2O3 + 9Fe c.
Balance: CH3OH + O2 CO2 + H2O First balance H (it appears once on each side) by writing a 2 in front of H2O: CH3OH + O2 CO2 + 2H2O To avoid fractional coefficients for O, multiply the equation by 2: 2CH3OH + 2O2 2CO2 + 4H2O Finally, balance O by changing cha nging 2O2 to '3O2'; this balances the entire equation: e quation: 2CH3OH + 3O2 2CO2 + 4H2O
Chapter 2: Atoms, Molecules, and Ions
d.
49
Balance: P4O10 + H2O H3PO4 First balance P (it appears once on each side) by writing a 4 in front of H3PO4: P4O10 + H2O 4H3PO4 Finally, balance H by writing a 6 in front of H2O; this balances the entire equation: P4O10 + 6H2O 4H3PO4
e.
Balance: PCl5 + H2O H3PO4 + HCl First balance Cl (it appears once on each side) by writing a 5 in front of HCl: PCl5 + H2O H3PO4 + 5HCl Finally, balance H by writing a 4 in front of H2O; this balances the entire equation: PCl5 + 4H2O H3PO4 + 5HCl
2.98.
a.
Balance: Ca3(PO4)2 + H3PO4 Ca(H2PO4)2 First balance Ca (appears only once on each side) by writing a 3 in front of Ca(H2PO4)2; Ca3(PO4)2 + H3PO4 3Ca(H2PO4)2 Finally, balance P by writing a 4 in front of H3PO4; this balances the entire e ntire equation: Ca3(PO4)2 + 4H3PO4 3Ca(H2PO4)2
b.
Balance: MnO2 + HCl MnCl2 + Cl2 + H2O First balance O (appears only once on each side) by writing a 2 in front of H2O: MnO2 + HCl MnCl2 + Cl2 + 2H2O Finally, balance H and Cl by writing a 4 in front of HCl to balance the entire equation: MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
c.
Balance: Na2S2O3 + I2 NaI + Na2S4O6 First balance S by writing a 2 in front of Na2S2O3: 2Na2S2O3 + I2 NaI + Na2S4O6 Finally, balance Na by writing a 2 in front fr ont of NaI; this balances the entire equation: 2Na2S2O3 + I2 2NaI + Na2S4O6
d.
Balance: Al4C3 + H2O Al(OH)3 + CH4 First balance Al with a 4 in front of Al(OH)3, and balance C with a 3 in front of CH4: Al4C3 + H2O 4Al(OH)3 + 3CH4 Finally, balance H and O with a 12 in front of H2O; this balances the entire equation: Al4C3 + 12H2O 4Al(OH)3 + 3CH4
50
Chapter 2: Atoms, Molecules, and Ions
e.
Balance: NO2 + H2O HNO3 + NO First balance H with a 2 in front of HNO3: NO2 + H2O 2HNO3 + NO Finally, balance N with a 3 in front of NO2; this balances the entire equation: 3NO2 + H2O 2HNO3 + NO
2.99.
s) + H2SO4(aq) CaSO4( s s) + H3PO4(aq) Balance: Ca3(PO4)2( s
Balance Ca first with a 3 in front of CaSO4: s) + H2SO4(aq) 3CaSO4( s s) + H3PO4(aq) Ca3(PO4)2( s
Next, balance the P with with a 2 in front of of H3PO4: s) + H2SO4(aq) 3CaSO4( s s) + 2H3PO4(aq) Ca3(PO4)2( s
Finally, balance the S with a 3 in front of H2SO4; this balances the equation: s) + 3H2SO4(aq) 3CaSO4( s s) + 2H3PO4(aq) Ca3(PO4)2( s s) + H2O(l ) NaOH(aq) + H2( g g ) 2.100. Balance: Na( s
Balance H first with a 2 in front of H2O and NaOH: Na + 2H2O 2NaOH + H2 Then, balance Na with a 2 in front of Na; this balances the equation: s) + 2H2O(l ) 2NaOH(aq) + H2( g g ) 2Na( s g ) + BaCl2(aq) + H2O(l ) 2.101. Balance: NH4Cl(aq) + Ba(OH)2(aq) NH3( g
Balance O first with a 2 in front of H2O: NH4Cl + Ba(OH)2 NH3 + BaCl2 + 2H2O Balance H with a 2 in front of NH4Cl and a 2 in front of NH3; this balances the equation: 2NH4Cl(aq) + Ba(OH)2(aq) 2NH3( g g ) + BaCl2(aq) + 2H2O(l ) s) + PbSO4( s s) Pb(l ) + SO2( g g ) 2.102. Balance: PbS( s
Balance S first with a 2 in front of SO2: PbS + PbSO4 Pb + 2SO2 Balance Pb with a 2 in front of Pb; this balances the equation: g ) s) + PbSO4( s s) 2Pb(l ) + 2SO2( g PbS( s
Chapter 2: Atoms, Molecules, and Ions
■
51
SOLUTIONS TO GENERAL PROBLEMS
2.103. Calculate the ratio ratio of oxygen for 1 g (fixed amount) of nitrogen nitrogen in both compounds: compounds: A:
2.755g 2.755gO 2.2844g 2.2844gO = 1.206 g N 1gN
B:
4.714g 4.714gO 2.8552g 2.8552gO = 1.651 g N 1gN
Next, find the ratio of oxygen oxygen per gram of nitrogen for the two compounds. compounds. 2.8552g 2.8552gO 1.2498g 1.2498gO gOinB/1gN = = 2.2844 g O 1g O g O in A/1 g N B contains 1.25 times as many O atoms as A does (there are five O's in B for every four O's in A). 2.104. Calculate the ratio ratio of oxygen for 1 g (fixed amount) of sulfur sulfur in both compounds: compounds: A:
1.811g 1.811gO 1.4966g 1.4966gO = 1.210 g S 1gS
B:
1.779g 1.779gO 0.99775g 0.99775gO = 1.783 g S 1gS
Next, find the ratio of oxygen oxygen per gram of sulfur for the two compounds. compounds. 1.4966g 1.4966gO 1.4999g 1.4999gO gOinA/1gS gS = = 0.99775 g O 1g O g O in B/1 g S A contains 1.50 times as many O atoms as B (there are a re three O's in A for every two O's in B). 2.105. The smallest difference is between 4.80 1019 C and 6.40 1019 C and is equal to 1.60 1019 C. If this charge is equivalent to one electron, the number of excess electrons on a drop may be found by dividing the negative charge by the charge of one electron. 4.80 1019 C 1.60 1019 C
= 3.00 3 electrons
6.40 1019 C Drop 2: 1.60 1019 C
= 4.00 4 electrons
9.60 1019 C Drop 3: 1.60 1019 C
= 6.00 6 electrons
1.28 1018 C 1.60 1019 C
= 8.00 8 electrons
Drop 1:
Drop 4:
2.106. The smallest difference difference in charge charge for the oil oil drop is 1.85 x 1019; assume this is the fundamental unit of negative charge. Use this to divide into each ea ch drop's charge: Drop 1:
5.55 1019 C 1.85 1019 C
= 3.0 3 electrons electrons
Drop 2:
9.25 1019 C 1.85 1019 C
= 5.0 5 electrons electrons
Drop 3:
1.11 1018 C 1.85 1019 C
= 6.0 6 electrons electrons
52
Chapter 2: Atoms, Molecules, and Ions
Drop 4:
1.48 1018 C 1.85 1019 C
= 8.0 8 electrons electrons
2.107. For the Eu atom to be neutral, the number number of electrons must must equal the number number of protons, so a 3+ neutral europium atom has 63 electrons. The 3+ charge on the Eu indicates there are three more protons than electrons, electrons, so the number number of electrons is 63 63 3 = 60. 2.108. For the Cs atom to be neutral, the number number of electrons must must equal the number number of protons, so a + neutral cesium atom has 55 electrons. The 1+ charge on the Cs indicates there is one more proton than electrons, electrons, so the number number of electrons is 55 1 = 54. 2.109. The number number of protons protons = mass number number number of neutrons = 81 46 = 35. The element with with Z = 35 is bromine (Br). The ionic charge charge = number number of protons number number of electrons = 35 36 = 1. Symbol:
81 35
Br . Br .
2.110. The number number of protons protons = mass number number number of neutrons = 74 51 = 23. The element with with Z = 23 is vanadium (V). The ionic charge charge = number number of protons number number of electrons = 23 18 = +5. Symbol:
74 23
V5 .
2.111. The sum of the fractional fractional abundances abundances must must equal 1. Let y equal the fractional abundance of 151Eu. Then the fractional abundance of 153Eu equals (1 y). We write one equation in one unknown: Atomic weight = 151.9641 = 150.9196 y + 152.9209(1 y) -0.9598 = -2.0013 y y =
-0.9568 = 0.47809 -2.0013
The fractional abundance of 151Eu = 0.47809 = 0.4781. The fractional abundance of 153Eu = 1 0.47809 = 0.52191 0.52191 = 0.5219. 0.5219. 2.112. As in the previous previous problem, the sum of the fractional abundances abundances must equal 1. Thus, the y equal the fractional abundance of one isotope can be expressed in terms of the other. Let y abundance of Ag-107. Then the fractional abundance of Ag-109 equals (1 y). We can write one equation in one unknown: Atomic weight = 107.87 = 106.91 y + 108.90(1 y) 107.87 = 108.90 108.90 1.99 y y =
108.90108.90-107.87 = 0.51758 1.99
The fractional abundance of Ag-107 = 0.51758 = 0.518. The fractional abundance abundance of Ag-109 Ag-109 = 1 0.51758 = 0.48241 0.48241 = 0.482.
Chapter 2: Atoms, Molecules, and Ions
2.113. a.
Bromine, Br
b.
Hydrogen, H
c.
Niobium, Nb
d.
Fluorine, F
2.114. a.
Bromine, Br
b.
Mercury, Hg
c.
Aluminum, Al
d.
Potassium, K
2.115. a.
Chromium(III) ion
b.
Lead(IV) ion
c.
Titanium(II) Titanium(II) ion
d.
Copper(II) Copper(II) ion
2.116. a.
Manganese(II) Manganese(II) ion
b.
Nickel(II) ion
c.
Cobalt(II) ion
d.
Iron(III) ion
2.117. All possible ionic compounds: compounds: Na2SO4, NaCl, CoSO4, and CoCl2. 2.118. All possible possible ionic ionic compounds: compounds: MgS, MgS, Mg(NO Mg(NO3)2, Cr 2S3, and Cr(NO3)3. 2.119. a.
Tin(II) phosphate
b.
Ammonium nitrite
c.
Magnesium hydroxide
d.
Nickel(II) sulfite
2.120. a.
Copper(II) Copper(II) nitrite
b.
Ammonium phosphide
c.
Potassium sulfite
d.
Mercury(II) nitride
2.121. a.
Hg2S [Mercury(I) exists as the polyatomic Hg22 ion (Table 2.6).]
b.
Co2(SO3)3
c.
(NH4)2Cr 2O7
d.
AlF3
53
54
Chapter 2: Atoms, Molecules, and Ions
2.122. a.
H2O2
b.
Mg3(PO4)2
c.
Pb3P4
d.
CaCO3
2.123. a.
Arsenic tribromide
b.
Hydrogen telluride (dihydrog ( dihydrogen en telluride)
c.
Diphosphorus pent(a)oxide
d.
Silicon dioxide
2.124. a.
Chlorine tetrafluoride
b.
Carbon disulfide
c.
Phosphorus trifluoride
d.
Sulfur hexafluoride
2.125. a.
Balance the C and H first: C2H6 + O2 2CO2 + 3H2O Avoid a fractional coefficient for O on the left by doubling all coefficients except O2's, and then balance the O's: 2C2H6 + 7O2 4CO2 + 6H2O
b.
Balance the P first: first: P4O6 + H2O 4H3PO3 Then balance the O (or H), which also gives the H (or O) balance: P4O6 + 6H2O 4H3PO3
c.
Balancing the O first is the the simplest simplest approach. approach. (Starting with K and Cl and then proceeding to O will cause the initial coefficient for KClO3 to be changed in balancing O last.) 4KClO3 KCl + 3KClO4
d.
Balance the N first: (NH4)2SO4 + NaOH 2NH3 + H2O + Na2SO4 Then balance the Na, followed by O; this also balances the H: (NH4)2SO4 + 2NaOH 2NH3 + 2H2O + Na2SO4
e.
Balance the N first: 2NBr 3 + NaOH N2 + NaBr + HOBr Note that NaOH and HOBr HOBr each have one one O and that NaOH and NaBr each have one one Na; thus the coefficients of all three are equal; from 2NBr 3, this coefficient must be 6Br/2 = 3: 2NBr 3 + 3NaOH N2 + 3NaBr + 3HOBr
Chapter 2: Atoms, Molecules, and Ions
2.126. a.
55
Balance the Na first: 2NaOH + H2CO3 Na2CO3 + H2O Then balance the H; this also also balances the O: 2NaOH + H2CO3 Na2CO3 + 2H2O
b.
Balance the Cl with with a 4 in front of the HCl; HCl; then balance the O's with a 2 in front of H2O: SiCl4 + 2H2O SiO2 + 4HCl
c.
Balance the O first with an 8 in front front of CO; then balance balance the the C with an 8 in front of of C: Ca3(PO4)2 + 8C Ca3P2 + 8CO
d.
Balance the O by multiplying multiplying O2 by 3 and doubling both both products to give give a total of six O's on both sides of the equation: equation: H2S + 3O2 2SO2 + 2H2O Then balance H and S with a 2 in front of H2S: 2H2S + 3O2 2SO2 + 2H2O
e.
Since the reaction has two N's on the left left and and one one N on on the the right, right, try a tentative tentative N-balancing by writing a 2 in front of NO2: N2O5 2NO2 + O2 Now there are five O's O's on the left and six O's O's on the right. Balance the O's with a ½ in front of O2; this gives N2O5 2NO2 + ½ O2 Because it is customary customary to balance chemical equations with whole number coefficients, multiplying multiplying each of the reactant and product coefficients by 2 yields the desired result: 2N2O5 4NO2 + O2
2.127. Let: x = number of protons. Then 1.55 x is the number of neutrons. Since the mass number is 235, you get 235 = x + 1.55 x = 2.55 x Thus, x = 92.157, or 92. The element is uranium (U). Since the ion has a +4 charge, there are 88 electrons. 2.128. Let: x = number of protons. Then 1.30 x is the number of neutrons. Since the mass number is 85, you get 85 = x + 1.30 x = 2.30 x Thus, x = 36.95, or 37. The element is rubidium (Rb). Since the ion has a +1 charge, there are 36 electrons. 2.129. The average average atomic atomic weight weight would be Natural carbon: 12.011 1/2
=
6.005500
Carbon-13: 13.00335 1/2
=
6.501675
Average
=
12.507175
The average atomic weight of the sample is 12.507 amu.
56
Chapter 2: Atoms, Molecules, and Ions
2.130. The average average atomic weight would be Natural chlorine: 35.4527 1/2 =
17.7263500
Chlorine-35: Chlorine-35: 34.96885 1/2
17.4844250
=
Average
=
35.2107750
The average atomic weight of the sample is 35.2108 amu. 2.131. The provisional name for element 117 is ununseptium. ununseptium. The name is arrived at by replacing each of the digits of the atomic number with a root, un for 1 and sept for 7, and then adding the ium . suffice – ium 2.132. The target element was Bk-249 and the beam element was Ca-48.
■
SOLUTIONS TO STRATEGY STRATEGY PROBLEMS PROB LEMS
2.133. SO3, sulfur trioxide; NO2, nitrogen dioxide; dioxide; PO34 , phosphate ion; N2, nitrogen; Mg(OH)2, magnesium hydroxide 2.134. The unknown metal, metal, M, is a cation with a 2+ charge. An example example is magnesium. magnesium. 2.135. The name of the product product is aluminum oxide. The reaction is s) + 3O2(g) 2Al2O3( s s) 4Al( s g ) + 5O2( g g ) 4NO( g g ) + 6H2O(l ) 2.136. 4NH3( g x) = 37.45 amu 2.137. (0.7721)(37.24 amu) + (1 0.7721)( x x =
37.45 (0.7721)(37.24)
= 38.161 amu = 38.2 amu
(1 0.7721) 2.138. Sulfur has atomic number 16, so S2+ has 16 minus 2 or 14 electrons, which is the number of neutrons in the unknown ion. The number of protons is 27 minus 14 = 13, which is the atomic number, so the element is aluminum. aluminum. The number of electrons is 13 3 = 10. 3 ions = 1.95 1021 ions 2.139. 6.5 1020 formula units CaCl2 1 formula unit 2.140. MgCO3, magnesium carbonate Mg3 N2, magnesium nitride Cr 2(CO3)3, chromium(III) chromium(III) carbonate CrN, chromium(III) chromium(III) nitride
Chapter 2: Atoms, Molecules, and Ions
57
2.141. SO3, sulfur trioxide HNO2, nitrous acid Mg3 N N2, magnesium nitride HI(aq), hydroiodic acid Cu3(PO4)2, copper(II) phosphate CuSO45H2O, copper(II) sulfate pentahydrate 2.142. HIO3, iodic acid NaIO4, sodium periodate Mg(IO2)2, magnesium iodite Fe(IO2)3, iron(III) iodite 2.143. a.
An aqueous solution of lead(II) chloride is mixed with an aqueous solution of sodium sulfide to form an aqueous solution of sodium chloride and a lead(II) sulfide precipitate.
b.
When gaseous sulfur sulfur trioxide is passed passed into liquid liquid water an aqueous solution solution of sulfuric sulfuric acid is formed.
c.
Graphite is combusted in an oxygen atmosphere to form gaseous carbon dioxide.
d.
Gaseous hydrogen iodide forms when hydrogen gas and gaseous iodine are mixed.
2.144. Cl2(g) + 2K(s) 2KCl(s) 2.145. Each 1H216O molecule contains 8 neutrons, 10 protons, and 10 electrons. # neutrons neutrons in 6.0 1023 molecules = 8 (6.0 1023 ) = 4.8 1024 neutrons # protons protons in 6.0 1023 molecules = 10 (6.0 1023 ) = 6.0 1024 protons Because the water molecules molecules are neutrally charged charged there must must also be 6.0 1024 electrons. 2.146. a.
hydrogen chloride
b.
hydrobromic acid
c.
hydrogen fluoride
d.
nitric acid
2.147. We are told that a 238U nucleus decays by emitting a 4He atom while the remaining subatomic particles remain intact. intact. In equation form, form, we can write this as follows: follows: 238 92
U
2
4 He + z Xy
Such nuclear decay processes must follow conservation laws. In this regard, the total mass number of the reactants must equal that of the products. It follows that if 238 = 4 + y, then y = 234. Likewise, the total atomic number of the reactants must equal that of the products. Again, if 92 = 2 + z, then z = 90. The symbol for the other nuclide being produced in this decay process is 234 90Th . Thorium (Th) is produced. s) 6 H2O(l ) + Mg3(PO4)2( s s) 2.148. 2 H3PO4(aq) + 3 Mg(OH)2( s
58
■
Chapter 2: Atoms, Molecules, and Ions
SOLUTIONS TO CAPSTONE PROBLEMS
2.149. The spheres occupy occupy a diameter diameter of 2 1.86 Å = 3.72 Å. The line line of sodium atoms would would stretch a length of 3.72A 3.72A 2.619 1022 Na atoms = 9.742 1022 Å 1 Na atom Now, convert this to miles. Length =
22
9.742 10 Å
1010 m 1A
1 mile 1.609 103 m
= 6.055 109 miles = 6.06 109 miles
2.150. The spheres occupy occupy a diameter diameter of 2 0.99 Å = 1.98 Å. The line line of chlorine chlorine atoms atoms would stretch a length of 1.98A 1.98A Length = 1 Cl atom
1.699 x 1022 Cl atoms 0.5 g Cl = 1.682 1022 Å 1.000 g Cl
Now, convert this to miles. 22
1.682 10 Å
1010 m 1A
1 mile 1.609 103 m
= 1.045 109 miles = 1 109 miles
s) NiSO46H2O( s s) + H2O( g g ) [8.753 2.151. NiSO47H2O( s
g] = [8.192 g + (8.753 8.192 = 0.561 g) ] The 8.192 g of NiSO46H2O must must contain 6 0.561 = 3.366 3.366 g H2O. Mass of anhydrous NiSO4 = 8.192 g NiSO46H2O 3.366 g 6H2O = 4.826 g NiSO4 2.152. The formula formula for cobalt(II) cobalt(II) sulfate heptahydrate heptahydrate is CoSO47H2O and the formula for cobalt(II) sulfate monohydrate is CoSO4H2O. The equation for the described heating process is CoSO47H2O( s s) CoSO4H2O( s s) + 6H2O( g g ) Using the law of conservation of mass with the data provided, [3.548 g heptahydrate] = [2.184 g monohydrate monohydrate + (3.548 2.184 = 1.364 g H2O )] Mass of one H2O unit per 3.548 g of CoSO47H2O = 1.364 1.364 g 6 = 0.22733 0.22733 g Mass of anhydrous CoSO4 = 2.184 g CoSO4H2O 0.22733 g H2O = 1.9567 g = 1.957 g CoSO4 1.330g 1.330gO = 0.799995 g = 0.8000 g oxygen 2.153. Mass of O = 0.6015 L 1L 15.999 amu O
3.177g 3.177gX = 63.536 amu X = 63.54 amu 0.799995 g O
The atomic weight of X is 63.54 amu; X is copper.
Chapter 2: Atoms, Molecules, and Ions
2.154. Mass of Cl Cl = 0.4810 L
35.45 amu Cl
2.948g 2.948gCl 1L
59
= 1.41799 g = 1.418 g chlorine
4.315g 4.315gX = 107.88 amu X = 107.9 amu 1.41799 g Cl
The atomic weight of X is 107.9 amu; X is silver. 2.155. (a)
For the first species, since the net charge is zero, the number number of protons in the nucleus (and the atomic number of the nucleus) equals the number of electrons, 32. The element’s name and symbol are, respectively, germanium and Ge, i.e., a metalloid found in Group/family Group/family 4A. With the mass number being the number of protons (32) and neutrons in the nucleus, the number neutrons in the nucleus equals 73 – 32 32 = 41. Hence, the complete symbol symbol for the charge-neutral 73 particle would be 32 Ge . For the second species, we gather a large amount of information from the symbol symbol given for the particle. “I” is the symbol for iodine, a nonmetal nonmetal halogen associated with Group 7A. The left handed subscript indicates both the number of protons in the nucleus (53) and the atomic number (53). The upper right superscript indicates a charge of 1-; thus, the electron count (54) is one higher than the proton count (53). With the mass number number (131) equaling the number number of neutrons plus protons (53), the the number of neutrons neutrons in the particle equals equals 131-53 = 78. These results are summarized in the following table:
Name or Group # of Element
Element Name
Metal,
Group 4A
germanium
metalloid
73 32
Halogen
iodine
nonmetal
13 1
Metalloid Or
Symbol
Mass
Atomic Number Number Number Net 1 1 of eCharge (example Number Number of 0 n of 1 p in Nucleus 31 3 in 15 P ) Nucleus
Nonmetal? Ge
I
53
73
32
41
32
32
0
131
53
78
53
54
1-
Group 7A (b)
For the first species, we are given the atomic atomic number, 34, which also equals the number number of protons in the nucleus (34). The element element is selenium, a nonmetal Group 6A chalcogen. Since the particle has a charge of 2-, it must have two more electrons (36) associated with the particle. With the mass number (80) equaling the number of neutrons (46) plus the number of protons (34), the complete symbol for the ion would be 8034 Se2 . For the second species, we have a 2+ charged ion; hence, there must be two more protons (56) than electrons (54) associated with the particle. Since the proton count equals the atomic number (56), the element is barium (Ba), an alkaline earth metal of Group 2A. Noting the mass number of 138 equals the number of protons (56) plus neutrons, 82 (=138-56) neutrons are in the nucleus. Hence, the complete symbol for the ion would be 13856 Ba2 .
60
Chapter 2: Atoms, Molecules, and Ions
These results are summarized in the following table: Name or Group # of Element
Element Name
Metal, Metalloid Or
Symbol
Mass
Atomic Number Number Number Net 1 1 Charge of e(example Number Number of 0 n of 1 p in Nucleus 31 3 in 15 P ) Nucleus
Nonmetal? Chalcogen selenium
Nonmetal
80 34
Se 2
80
34
46
34
36
2-
138
56
82
56
54
2+
Group 6A Alkaline Earth Metal
barium
Metal
138 2 56 Ba
Group 2A 2.156. The term “molecule” is used for CH3CH2CH2OH because only covalent bonding forces are holding nonmetal nonmetal atoms together to yield a distinctly unique molecular structure. The term “formula unit” is used for Pb3(PO4)4·6H2O to account for the extended presence of ionic bonding forces holding lead(IV) lead(IV) cations and phosphate anions together. together. This does not disallow the concurrent presence of covalent bonding forces which allow the phosphate ions and hydrate water molecules to be viewed semi-independently. semi-independently. The distinction becomes clearer if the dehydrated form of Pb3(PO4)4·6H2O is considered, i.e., Pb3(PO4)4. In the crystalline c rystalline form, this ionic substance could be represented in an infinite number of ways, e.g., Pb3(PO4)4, (Pb3(PO4)4)2, (Pb3(PO4)4)8, (Pb3(PO4)4)50,000,000, etc. Because an ionic crystal is viewed as a broadly extended array of ions, and not as distinct molecules, molecules, the general rule is to present ionic substances using their simplest, or empirical formula, which is often referred to as a formula unit. Each of the 4 molecules of CH3CH2CH2OH contain 12 atoms and each of the 5 formula units of Pb3(PO 4) 4·6H 2O contain 41 atoms. This yields a total of of 253 atoms: 12 atoms + 5 Pb3(PO4)46H2O f.u. 41 atoms = 253 atoms 4 CH3CH2CH2OH molecules x 1 molecule 1 f.u. In terms of proton count, 12 C atoms at oms each contain 6 protons, 92 H at oms each contain 1 proton, proto n, 114 O atoms ato ms each eac h contain cont ain 8 protons, 15 Pb atoms each e ach contain contai n 82 protons, protons , and an d 20 P atoms each contain 15 protons. This results in 2606 protons in the mixture. As for the electron count, since t he substances are electri cally neutra l, there must be the same number of electrons as protons. Hence, there are 2606 electrons in the mixture. To determine the theoretical maximum number of O3 molecules that could be made from the mixture, it is useful to first deter mine the number of O atoms present: 1 O atom + 5 Pb (PO ) 6H O f.u. 22 O atoms 3 4 4 2 = 114 O atoms 4 CH3CH2CH2OH molecules x 1 molecule 1 f.u. With each O3 molecule containing three O atoms, 114 O atoms would yield 38 O3 molecules: 114 O atoms x
1O3 molecule = 38 O3 molecules 3 O atoms
Chapter 2: Atoms, Molecules, and Ions
61
The chemical symbol for potassium is K. Since neither of the two substances in the sample have K in their formulas, we conclude there are no K atoms in the mixture. Because the sample contains 5 formula units of Pb3(PO4)46H2O, with each containing 3 lead atoms, there are 15 Pb atoms in the mixture. The correct name of Pb3(PO4)46H2O is lead(IV) phosphate hexahydrate. The oxoanion present in Pb3(PO4)46H2O is the phosphate ion which corresponds to the phosphoric acid, H3PO4. 2.157. (a) It is easiest to initially initially write a combustion combustion equation with only oxygen oxygen as the reactant as follows: C11H7S + O2 CO2 + H2O + SO2 Balancing the carbon atoms requires the placement placement of a coefficient of 11 in front fr ont of the CO2. Likewise, the sulfur atoms are balanced by placing an appropriate coefficient (1 in this case) in front of the SO2: C11H7S + O2 11 CO2 + H2O + SO2 Next, we attempt to balance the hydrogen atoms atoms but quickly realize the only way to do so would require placement of a fractional coefficient in front of H2O. To sidestep this, the portions of the equation that have already been addressed are multiplied by 2: 2 C11H7S + O2 22 CO2 + H2O + 2 SO2 We can now easily see that 14 reacting H atoms would produce 7 water product molecules: 2 C11H7S + O2 22 CO2 + 7 H2O + 2 SO2 At this stage the only remaining element to be balanced is oxygen. With 55 oxygen atoms on the product side, we need an equal number number on the reactant side. Recognizing Recognizing every every ½ of an O2 molecule is equivalent to 1 oxygen atom, placement of a coefficient of 55/2 in front of O2 completes the balancing: 2 C11H7S + 55/2 55/2 O2 22 CO2 + 7 H2O + 2 SO2 Again, it is easier to modify the equation equation such that only integer coefficients are present by once again multiplying by 2: 4 C11H7S + 55 O2 44 CO2 + 14 H2O + 4 SO2 Careful inspection of this equation will show that it is balanced but we have yet to include the nitrogen that also moves through the combustion system. To achieve the desired result, we add 3.76 times as many N2 molecules as oxygen molecules, and being generally inert, we include the N2 on the product side as well. That is, 4 C11H7S + 55 O2 + 55(3.76) N2 44 CO2 + 14 H2O + 4 SO2 + 55(3.76) N2 (b) In the case of 120% stoichiometric stoichiometric combustion, we need only to multiply the O2 and N2 coefficients by 1.20, and also remember to include the excess O2 on the product side: 4 C11H7S + 55(1.20) O2 + 55(3.76)(1.20) N2 44 CO2 + 14 H2O + 4 SO2 + 55(3.76)(1.20) N2 + 55(0.20) O2 Further simplification yields the following equation: 4 C11H7S + 66 O2 + 248.16 N2 44 CO2 + 14 H2O + 4 SO SO2 + 248.16 N2 + 11 O2
62
Chapter 2: Atoms, Molecules, and Ions
2.158. (a) See the solution solution to problem 2.111. 2.111. There it is shown that that the fractional abundance of 151Eu = 0.47809 = 0.4781, and the fractional abundance of 153Eu = 1 0.47809 = 0.52191 0.52191 = 0.5219. 0.5219. (b) See the graph below:
In a mass spectrometer experiment, the two blue solid lines would appear in the mass spectrum of an elemental europium sample. In contrast, it is the x-value of the dotted red line which is presented in the periodic periodic table of atomic atomic weights for europium. europium. 2.159. Although there there are ways to solve solve this problem, the approach approach here utilizes utilizes dimensional analysis analysis to first determine the number of graduating students required to piece together the atomic gold strings ascending to the top of the flagpole as follows: 172 ft x
12 in 2.54 cm 1m 1012 pm 1 Au atom atom 1 graduate = 1.506 x 104 graduates x x x x x 7 1 ft 1 in 100 cm 1m 348 pm 1 x 10 Au atoms
Noting each class year year produces 250 graduates, graduates, the number number of years required to accomplish accomplish the stated goal is readily calculated as follows: 1year 1.506 x 104 graduates x 60.3 years 250 gr aduates With the class of 2018 being the inaugural group to begin the process, the class of 2019 would be the second year and so forth. Counting forward, the 60th year would be the class of 2077. Since this class would still come shy of the top of the flagpole, one more year would be required to attach the extended length of atomic gold strings to the top of the fla gpole. Thus, the class of 2078 would be the class recognized for finally achieving the initial goal. 2.160. A: (a) Complete combustion of an organic compound such as C5H10O refers to its reaction with oxygen (O2) to produce CO2 and H2O. We first balance the carbon atoms by recognizing that each molecule of C5H10O much produce 5 molecules of CO2: C5H10O +
O2 5 CO2 +
H2O
Next, we balance the hydrogen hydrogen atoms atoms by recognizing each molecule molecule of C5H10O must produce 5 molecules of H2O: C5H10O +
O2 5 CO2 + 5 H2O
Chapter 2: Atoms, Molecules, and Ions
63
Counting up the oxygen atoms atoms on the product side, we see there are 15 of them. Therefore, we must have 15 oxygen atoms on the reactant side. With one oxygen atom supplied by C5H10O, it is readily observed the other 14 oxygen atoms must be supplied by 7 oxygen molecules: C5H10O + 7 O2 5 CO2 + 5 H2O A careful count of all atoms of each type will show that this reaction is now balanced. (b) To approach this reaction requires a bit of nomenclature regarding the formula for lead(IV) nitride. The name lead(IV) refers to the Pb4+ ion while nitride refers to the N3- ion. Combining these two ions to form an electrically neutral species results in the formula for Pb3 N N4. This gives us another clue to the reaction being considered: Pb(s) +
Pb3 N N4
Considering there is only one other assumed reactant, the most likely candidate is nitrogen gas: Pb(s) +
N2 Pb3 N N4
This reaction is finally balanced by direct inspection: 3 Pb(s) Pb(s) + 2 N2 Pb3 N N4 B: (a) Complete combustion of an organic compound such as C8H18O2 refers to its reaction with oxygen (O2) to produce CO2 and H2O. We first balance the carbon atoms by recognizing that each molecule of C8H18O2 much produce 8 molecules of CO2: C8H18O2 +
O2 8 CO2 +
H2O
Next, we balance the hydrogen hydrogen atoms atoms by recognizing each molecule of C8H18O2 must produce 9 molecules of H2O: C8H18O2 +
O2 8 CO2 + 9 H2O
Counting up the oxygen atoms atoms on the product side, we see there are 25 of them. Therefore, we must have 25 oxygen atoms on the reactant side. With two oxygen atoms supplied by C8H18O2, it is readily apparent the other 23 oxygen atoms must be supplied by 11.5 (or 23/2) oxygen molecules: C8H18O2 +
23 O2 8 CO2 + 9 H2O 2
Multiplying all of the coefficients by 2 provides a balanced reaction with integer coefficients: 2 C8H18O2 + 23 O2 16 CO2 + 18 H2O (b) To approach this reaction requires some nomenclature regarding the formula for mercury(I) mercury(I) 2 phosphide, i.e., a compound composed the Hg2 ion and the P3- ion. To be electrically neutral, the relevant formula would be (Hg2)3P2. Placing this into the skeleton equation provided yields the following: +
P4 (Hg2)3P2
Assuming mercury, mercury, Hg, to be the only other assumed reactant, the reaction skeleton is further constructed: Hg +
P4 (Hg2)3P2
64
Chapter 2: Atoms, Molecules, and Ions
Since each formula unit of (Hg2)3P2 contains 2 phosphorus atoms, the P4: (Hg2)3P2 ratio must be 1:2 in the final balanced reaction, that is: Hg + P4 2 (Hg2)3P2 Considering mercury mercury to be monatomic, and the fact that each e ach formula unit of (Hg2)3P2 associates with 6 Hg atoms, simple inspection provides the final balanced reaction as follows: follows: 12 Hg + P4 2 (Hg2)3P2
PART II
Features of the Text
In the preface to the first edition, we wrote, “Scientists delve into the molecular machinery of the biological cell and examine bits of material from from the planets planets of the solar solar system. In these endeavors endeavors chemistry is fundamental. The challenge for the instructors of introductory chemistry is to capture the excitement of these discoveries while giving students students a solid understanding of the basic principles and facts. The challenge for the students is to be receptive to a new way of thinking, which will allow them to be caught up in the excitement of discovery.” From the very first edition, our aim has always been to help instructors capture the excitement of chemistry and to teach students to “think chemistry chemistry.” Here are some of the features of the text that we feel are especially important in achieving these goals.
Chapter Opening Each chapter begins with a photo related to the content of the chapter. Under this photo on the chapteropening page is the Contents and Concepts section. This feature outlines the main sections of the chapter and and briefly previews the key concepts and relationships among topics, providing an outline for students’ reading and studying. You can use this yourself to quickly survey a chapter to see how it corresponds to your course plan and to see what deletions or changes of order you might wish to make. You can refer students to Contents and Concepts when you inform them of these deletions or changes. After the opening page, we begin each chapter with a chapter theme — something something specific specific that reveals Atoms, Molecules, Molecules, and and the real-world relevance of the chapter topic. For example, we open Chapter 2, Atoms, Ions, with a discussion of sodium, sodium, chlorine, and sodium chloride. This chapter theme then leads naturally into a series of questions (for instance, “How do we explain the differences in properties of different forms of matter?”) that we answer later in the chapter.
Vocabulary Chemists use words in a precise way, and it is important that students develop a chemistry vocabulary vocabulary that allows them to read and commun c ommunicate icate the subject effectively. When a new, important word is introduced in the text, we flag it by putting it in boldface type. The definition of the word will generally accompany it in the same sentence in italic type. For example, in Section 3.8, which discusses limiting reactants, we have the sentence: “The limiting reactant (or limiting reagent) is the reactant that is entirely consumed when a reaction goes to completion.” All these boldfaced words are collected at the end of each chapter in the list of Important Terms (opposite the Learning Objectives Objectives in A Checklist Checklist for Review). They also appear in the Glossary at the end of the book.
Problem-Solving Approach Learning chemistry requires the students’ active participation. For this purpose, we have included two types of in-chapter problems in which we ask students to participate by trying to do problems that exemplify the material they have just read. First are Exercises, which ask the student to solve a problem closely related to the previous text discussion. Most of these (unless fairly simple) are preceded by Examples that lead the student through the problem-solving process for a similar problem. Our goal is to help the student learn the problem-
4
Part II: Features of the Text
solving skills important important to absorbing the ideas presented. We believe that problem-solving is not a skill a student is born with; it requires models showing how it is done, and it requires practice. Each Example consistently uses our three-part problem-solving problem-solving process: a Problem Strategy, a Solution, and an Answer Check. By providing every Example with this three-part process (Problem Strategy, Solution, Answer Check), we hope to help students develop their problem-solving problem-solving skills: think how to proceed, solve the problem, check the answer. The Problem Strategy outlines the process that one typically works through in solving such a problem. Then the student is led through the step-by-step worked-out Solution. Solution. Finally the student is confronted with an Answer Check: Is this answer reasonable in terms of the general knowledge I have of the problem? This final phase of problem solving is a critical step often overlooked by students. Only consistent answer checking can lead to reliable results. Having worked through an example, example, the student can work the related Exercise on his or her own. For additional practice, similar similar end-of-chapter Practice Problems are identified at the end of the Exercise. The General Problems at the end of the chapter are similar to the Practice Problems, but are not keyed to the text Exercises. We also have yet another level of support for students in this problem-solving process. In every example, we have a Gaining Mastery Toolbox. At the beginning of each Toolbox we state the “big idea” involved in this Example problem (the Critical Concept ). ). Under this Critical Concept, we list prior topics needed to solve solve this problem problem (the (the Solution Essentials). While we believe in the importance of this coherent Example/Exercise approach, approach, we also think it is necessary to have students expand their understanding of the concepts. For this purpose we introduced a second type of in-chapter problem, Concept Checks. We have written these to force students to think about the concepts involved rather than to focus on the final result or numerical answer or to try to fit — or the problem to a memorized algorithm. algorithm. We want students to begin each problem by asking, “What are the chemical concepts that apply here?” Many of these problems involve visualizing a molecular situation since visualization is such a critical part of learning and understanding modern chemistry. For additional practice, similar types of end-of-chapter problems problems are provided, the Conceptual Problems.
Emphasis on Molecular Concepts Molecular concepts are central to modern chemistry, chemistry, and we have focused our presentation at the molecular level. We start building the molecular “story” in Chapter 1 (in the very first section), and by Chapter 2 we have developed the molecular view and have integrated it into the problem-solving problem-solving apparatus as well as into the text discussions. discussions. We continue in the following chapters to use the molecular view to strengthen chemical concepts. Most students are strongly visual in their learning, so we have used colorful molecular models liberally in these discussions. We have introduced electrostatic potential maps where pedagogically pedagogically relevant to show how electron density density changes across a molecule. This is especially helpful for visually demonstrating demonstrating things such as acid-base behavior.
Part II: Features of the Text
5
Chapter Essays We have two types of “boxed” essays to showcase chemistry as a modern science. One of these is the series of A Chemist Looks At essays, which cover up-to-date issues of science and technology. We have chosen topics that will engage students’ interest and at the same time highlight the chemistry involved. Icons are used to describe the content area (materials, environment, daily life, frontiers, and life science) being discussed. The essays show students that chemistry is a vibrant, constantly changing science that has relevance for our modern world. The essay “Gecko Toes, Sticky but not Tacky,” for example, describes the van der Waals forces used by gecko toes and their possible applications to the development of infinitely reusable tape or robots that can climb walls. Instrumental Methods Methods essays. These essays demonstrate the Also with this edition, we continue our Instrumental importance of sophisticated instruments for modern chemistry by focusing on instrumental methods used by research chemists, such as mass spectroscopy or nuclear magnetic resonance. Although short, these essays provide students with a level of detail to pique the students’ interest in this subject.
We recognize that classroom and study times are very limited and that it can be difficult to integrate this material into the course. For that reason, we have included two questions questions based upon upon each A Chemist Chemist Looks At At or Instrumental Instrumental Methods Methods essay. These questions, given at the end of the General Problems, Problems, promote the development development of scientific scientific writing skills, another area that often gets gets neglected in packed general chemistry courses. It is our hope that having brief essay questions ready to assign will allow both students and instructors to value the importance of this content and make it easier to incorporate it into their curricula. You might want to tell students that you may have similar questions on your exams e xams as a way to ensure that students read the essays.
A Checklist for Review This portion of the end-of-chapter material consists of three parts: 1.
Summary of Facts and Concepts. This summary presents a verbal review of the chapter. A
student can use each chapter summary as a way to review by trying to flesh out each statement as he or she reads along. 2.
Learning Objectives and Important Terms. The Learning Objectives and Important Terms for
each chapter section are given in table form, with the learning objectives listed listed on the left side and the important terms on the right side. Each Learning Objective describes words introduced, concepts discussed, and problem-solving problem-solving skills introduced (noting Example numbers). The Important Terms Terms is a list of all boldface terms in the text. Both the Learning Objectives and Important Terms Terms can be used as a way to view the structure of the chapter and can c an be used as a comprehensive review. 3.
Key Equations. Many chapters introduce one or more mathematical equations used in problem-
solving. Within the chapter, the key equations are shaded in color. They are listed in this section for review.
Questions and Problems After the Checklist for Review the chapter c hapter consists of a series of sections of questions and problems that offer a variety of types and difficulty.
Self-Assessment and Review Questions The Review Questions at the beginning of each of these sections are straightforward and can be used by a student to test his or her understanding of the chapter ideas. On the basis of student feedback, we
6
Part II: Features of the Text
developed conceptually focused multiple-choice multiple-choice questions to provide students with a quick opportunity for self-assessment. As they are intended primarily primarily for self-study, these questions have been included at the end of the Self-Assessment and Review Questions section. However, since multiple-choice multiple-choice questions are commonly included on exams, instructors may wish to assign them as homework or additional practice. Four Four of these questions questions are included in each chapter and answered in the back of the book. Solutions to all Self-Assessment and Review Questions are included in the Student and Complete Solutions Manuals.
Concept Explorations While we have included them in the end-of-chapter material, Concept Explorations are unlike any of the other end-of-chapter problems. These multi-part, multi-step problems are carefully structured activities developed to help students explore important chemical concepts — the key ideas in general chemistry — — the and confront common misconceptions misconceptions or gaps in learning. Often deceptively simple, simple, Concept Explorations ask probing questions questions to test the students’ understanding. Because we f eel eel strongly that, to develop a lasting conceptual understanding, understanding, students must think about questions in an unfamiliar way without jumping quickly to solutions and answer them without formulas or algorithms (or even even a calculator), we have purposely not included their answers in the Student Solutions Manual . As Concept Explorations are ideally used in an interactive classroom situation, we have reformatted them into workbook-style in-class in-class handouts with space for written answers (available as printable PDFs on the student and instructor websites) to facilitate their use in small groups. There are two Concept Explorations per chapter in the first nineteen chapters. (Their use is discussed in more detail in Part VIII Concept Explorations: Explorations: What Are They? See also Part IX Concept Explorations: Explorations: A List of Concepts and Misconceptions.)
Conceptual Problems These problems have the same intent as the in-chapter Concept Checks. They are meant to aid the student in learning the underlying concepts. In these, we ask students questions that require them to think and to solve problems by first asking: “What are the chemical concepts that apply here?” These questions are phrased to force a thoughtful answer rather than allow the student to apply a memorized algorithm. algorithm. Solutions to these appear in the Complete Solutions Manual .
Practice Problems A student can obtain practice with the problem-solving problem-solving skills exemplified by the in-chapter examples Problems available at the ends of the chapters. These problem sets by working through similar similar Practice Problems are divided into segments by topic heading. The problems are in matched pairs, and answers to all oddnumbered problems problems appear at the end of the book. Solutions to these odd-numbered problems appear in the Student Solutions Manual ; solutions to all problems appear in the Complete Solutions Manual .
General Problems These problems are similar to the Practice Problems, but have not not been divided divided by topic topic or keyed to related exercises. Each section ends with the boxed essay-related questions, each of which iscolorcoded to refer to a type of A Chemist Chemist Looks Looks at essay (life science, red; materials, brown; environment, Instrumental Methods essay (blue-green) on which it is green; frontiers, purple; daily life, orange) or Instrumental based. Odd-numbered Odd-numbered problems and the even-numbered even-numbered problems that follow are similar; answers answers to all odd-numbered odd-numbered problems except the essay questions are given in the back of the book. Solutions to these odd-numbered odd-numbered problems appear in the Student Solutions Manual ; solutions to all problems appear in the Complete Solutions Manual .
Part II: Features of the Text
Strategy Problems In addition to confronting common misconceptions, misconceptions, we also recognized a need to challenge students to build a conceptual conceptual understanding understanding rather than simply simply memorizing memorizing the algorithm from the matched pair and then applying it to a similar problem to get a solution. The Strategy Problems have been written to extend students’ problem-solving skills skills beyond those developed in the Practice and General Problems and to increase the level of rigor in the text. To work a Strategy Problem, students will need to think about the problem (which might involve several concepts or problem-solving problem-solving skills from the chapter), then solve it on their own without a similar problem from which to model their answer. For this reason, we have chosen explicitly not to include the answers to the Strategy Problems Problems in the Student Solutions Manual ; solutions to all problems appear in the Complete Solutions Manual.
Capstone Problems These are challenging problems that require students to combine skills, strategies, and concepts from different sections within a chapter, and from previous chapters, allowing students students to test their ability to integrate skills. Solutions to the odd-numbered odd-numbered problems appear in the Student Solutions Manual ; solutions to all problems appear in the Complete Solutions Manual .
7
2. Is I s otopes and Mas s S pectr pec trometr ometryy
Time: 45 minutes
Required chemicals and solutions solutions: None
Other required materials:
Metric ruler, 1/student if possible
Special note: None
Connections: Mass spectrometry has been used to
to help with medical diagnoses.
identify substances in the exhaled breath of patients
Date: Course/Section: Instructor:
Student name: Team members:
Is otop otopes es and Ma Mas s S pe pectrom ctromet etry ry Prelaboratory Assignment 1.
Suppose the mass mass spectrum of a hypothetical hypothetical monatomic element X contains a signal at mass number 13 and another of identical height at mass number 15. a.
Sketch the mass spectrum. Make sure each axis is properly labeled.
b.
How many many isotopes are present? Why? Because there are two signals for this monatomic element, there must be two tw o isotopes. One has mass number 13, and the other has mass number 15.
.
Isotopes and Mass Spectrometry
c.
What are the fractional abundances of the isotopes? Why? Because the signals have equal heights, the fractional abundances must be equal. Each one is 0.50.
2.
a.
Devise a general method for determining the fractional abundances of two or more isotopes from a mass spectrum. Your method must include some some means of measuring the the signals. You must state the type of measuring device that you will need to apply your method. You must also indicate how you will use the measurements to obtain the fractional abundances. The heights of all signals will be measured with a metric ruler. These heights will be added together. The fractional abundance abundance of an isotope will be equal to the th e height of its signal, divided by the sum of the heights of all of the signals.
b.
Test your method by determining determining the fractional abundances of neon’s isotopes from the mass spectrum in Figure 2.1. When you compare your results to known abundances, remember to take the precision of the measurements into account. Mass Number
Measurement with Units
20
6.75 cm
21
0.03 cm
22
0.70 cm
Calculation: 6.75 cm + 0.03 cm + 0.70 cm = 7.48 cm cm Fractional abundance of isotope with mass number 20: 6.75/7.48 = 0.902 mass number 21: 0.03/7.48 = 0.004 mass number 22: 0.70/7.48 = 0.094
Experiment 2
Comments: The agreement between these results and the known fractionalabundances fractionalabundances is excellent, as shown in the following comparison:
3.
a.
ass umber
Known
Calculated
20
0.9051
0.902
21
0.0027
0.004
22
0.0922
0.094
Explain fragmentation in a mass spectrometer. A molecule may fragment after a collision with a high-energy electron in the mass spectrometer. If this occurs, the mass spectrum will contain signals that are due to fragments of molecules, as well as a signal due to an unfragmented molecule.
b.
How will will fragmentation affect the mass spectrum of hydrogen chloride? Explain carefully. The mass spectrum is expected expect ed to consist of signals due to unfragmented H Cl+ and 37 35 37 H Cl+ as well as those for Cl+ and Cl+. 35
Student name:
Date: Course/Section: Instructor:
Team members:
Is otop otopes es and Ma Mas s S pe pectrom ctromet etry ry Results 1.
2.
Mercury peaks
Mass Number
Measurement with Units
198
2.29 cm
199
3.80 cm
200
5.25 cm
201
2.95 cm
202
6.70 cm
204
1.45 cm
Hydrogen chloride, HCl, peaks
Mass Number
Formula
35
35
36
H Cl
Cl
35
+
Measurement with Units 1.09 cm
+
6.72 cm
Experiment 2
37
38
37
Cl
37
+
H Cl
0.41 cm
+
2.14 cm
3.
Hydrogen bromide, HBr, peaks
Mass Number
79
Measurement with Units
Formula
_ 79Br+ 79
3.01 cm _ _ 3.01
+
80
H Br _
6.78 cm _ _ 6.78
81
81
2.95 cm _ _ 2.95
82
H Br _
Br
+
81
+
6.61 cm _ _ 6.61
How many isotopes of bromine are indicated? Explain. 79
+
81
+
There are two isotopes because there are signals for Br and Br as well as those for 79 + 81 + H Br and H Br .
4.
Bromine, Br 2 , peaks peaks (optional) (optional)
Mass Number
Formula 79
79
81
+
4.08 cm
+
4.08 cm
_ 79Br79Br+
3.35 cm
81
158
Br
Measurement with Units
Br
160
79
Br Br
81
+
6.71 cm
162
81
Br Br
81
+
3.35 cm
Isotopes and Mass Spectrometry
Questions 1.
Calculate the fractional fractional abundances of the isotopes of mercury, mercury, chlorine, and bromine.
Hg: 2.29 cm + 3.80 cm + 5.25 cm + 2.95 cm + 6.70 cm + 1.45 cm = 22.44 cm
Fractional abundance for mass no. 198: 2.2 9/22.44 = 0.102 199: 3.80/22.44 = 0.169 200: 5.25/22.44 = 0.234 201: 2.95/22.44 = 0.131 202: 6.70/22.44 = 0.299 204: 1.45/22.44 = 0.065
Cl from HCl: Using the largest signals: 6.72 cm + 2.14 cm = 8.86 cm Fractional abundance for mass mass no. 35: 6.72/8.86 = 0.758 37: 2.14/8.86 = 0.242
Br from HBr: Using the largest signals: 6.78 cm + 6.61 cm = 13.39 cm Fractional abundance for mass no. 79: 6.78/13.39 6.78/13.39 = 0.506 81: 6.61/13.39 = 0.494
2.
Calculate the atomic atomic weigh weightt of of mercury, chlorine, and bromine bromine from your data. Use mass mass numbers rather than exact masses. Compare your results to the actual atomic weights of these elements, and comment on any discrepancies.
Hg: (198)(0.102) + (199)(0.169) + (200)(0.234) + (201)(0.131) + (202)(0.299) + (204)(0.065) = 200.6 (known: 200.59)
Cl: (35)(0.758) + (37)(0.242) = 35.5 (known: 35.453)
Br: (79)(0.506) + (81)(0.494) = 80.0 (known: 79.904) The agreement between the calculated and known values is excellent.
Isotopes and Mass Spectrometry
3.
(Optional) Why does the mass spectrum of Br 2 contain three signals whose heights are almost al most in the ratio of 1:2:1? What are the origins of these signals? It may help to suppose that the fractional abundances of the isotopes are exactly equal. Then think about the probability of combining the various isotopes of bromine atoms into diatomic molecules. Finally, why does the spectrum contain two other signals of roughly equal height? What are the origins of these signals? To explain the 1:2:1 ratio of the signals at mass numbers 158, 160, and 162, we assume that 79 81 the fractional abundances of Br and Br are exactly equal (each with 0.50). Consider a 79 79 79 79 Br atom. It has an equal equ al probability of encountering another Br atom (to form Br Br) 81 79 81 or an Br atom (to form Br Br) because the fractional abundances of the two isotopes are equal. 81
81
Next, consider an Br atom. It has equal probability of meeting another Br atom (to form 81 81 79 81 79 79 81 Br Br) or a Br atom (to form Br Br, which is the same as Br Br). Because there are 79 81 79 79 81 81 two ways to get Br Br but only one way to get Br Br and only one way to get Br Br, the probability of finding these molecules should be in the ratio of 1:2:1. 79
+
81
+
Finally, the signals at mass numbers 79 and 81 are due to Br and Br . They have equal heights (or close to it) because be cause their fractional abundances are equal (or close to it).
Partner(s): Date:
Name: Instructor:
CHAPTER 2
Concept Explorations 2.25.
Average Atomic Mass
Part 1: 1:
Consider Consider the four identical spheres below, each with a mass of 2.00 g.
Calculate the average mass of a sphere in this sample.
Part 2: 2: Now
consider consider a sample sample that consists consists of four spheres, each each with a different different mass: mass: blue mass mass is 2.00 g, red mass is 1.75 g, green mass is 3.00 g, and yellow mass is 1.25 g. a.
Calculate the average mass of a sphere in this sample.
b.
How does the average mass mass for a sphere in this this sample sample compare with with the average mass of the sample that consisted just of the blue spheres? How can such different samples samples have their averages turn out the way they did?
Consider Consider two jars. One jar contains 100 blue spheres, spheres, and the other jar contains c ontains 25 each of red, blue, green, and yellow yellow colors mixed mixed together. Part 3: 3:
a.
If you were to remove 50 blue spheres from the jar containing just the the blue spheres, what would be total mass of spheres left in the jar? (Note that the masses of the spheres are given in Part 2.)
2
Chapter 2: Concept Explorations
b.
If you were to remove remove 50 spheres from from the jar containing the mixture (assume (assume you get a representative distribution distribution of colors), what would be the total mass of spheres left in the jar?
c.
In the case of the mixture mixture of spheres, spheres, does the average average mass of the spheresnecessarily represent the mass of an individual sphere in the sample?
d.
If you had 80.0 grams of spheres from the blue sample, how many spheres sphere s would you have?
e.
If you you had 60.0 grams grams of spheres spheres from the mixed-color mixed-color sample, how many many spheres spheres would you have? What assumption assumption did you make about your sample when performing this calculation?
Consider Consider a sample that consists of three green spheres and one blue sphere. The green mass is 3.00 g, and the blue mass is 1.00 g.
Part 4: 4:
a.
Calculate the fractional abundance of each sphere in the sample.
b.
Use the fractional abundance to calculate the average average mass of the spheres in this sample. sample.
c.
How are the ideas developed developed in this Concept Exploration Exploration related to the atomic masses of the elements?
3
Chapter 2: Concept Explorations
2.26
Model of the Atom
Consider the following depictions of two atoms, which have been greatly enlarged so you can see the subatomic particles.
a.
How many protons are present in atom A?
b.
What is the significance significance of the number number of protons protons depicted depicted in atom atom A or any atom? atom?
c.
Can you you identify the real element represented by the drawing of atom A? If so, what element element does it represent?
d.
What is the charge on element element A? Explain how you arrived at your answer.
e.
Write the nuclide symbol of atom A.
f.
Write the atomic symbol and the atomic number of atom B.
g.
What is the mass number of atom B? How does this mass number compare compare with that of atom A?
h.
What is the charge on atom B?
i.
Write the nuclide symbol of element B.
j.
Draw pictures like those above above of 6 3 Li+ and 6 3 Li− atoms. What are the mass number and atomic number of each of these atoms?
4
Chapter 2: Concept Explorations
k.
Consider the two atoms depicted in this problem problem and the two that you you just drew. What What is the total number of lithium isotopes depicted? How did you make your decision?
l.
Is the mass number number of an isotope isotope of an atom equal to the mass mass of the isotope of the atom? Be sure to explain your answer.
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